Instant skin condition with blisters (though only where his spit hit). Don’t ask me how this works I just thought it was cool.

Also, Devere does have control over this, his spit isn’t always toxic. XP

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↓ Transcript
Jed pulls out of Devere's grasp and reaches for the spot he spit on his face.
Jed: Ack! What the hell're you--

Jed rubs his fingers over the spot on his face and notices an unpleasant sensation as well as a subtle, sizzling-esque noise.
Jed: ...Ow...

Jed steps away and swings forward his upper body in pain, still holding onto his face, now with both hands.
Jed: Oww! Why's it burnin'?!
Devere observes in silence.

Jed straightens up and pulls his hands back revealing something like a red rash and large, oozing blisters on the spot where Devere had spit on him. He can't quite see what's happening but is horrified nonetheless. His hands also have some light rashes on them from touching the nocuous saliva.
Jed: M... My face! Oh god, what did you do?!

Jed turns back towards Sissy who has a hand over her mouth in mild concern at his predicament. The canary on her shoulder flies away.
Jed: H-Help! My skin's been befouled! I need healin'!

Devere shoves his hand into Jed's back with the intent to push him away from the area.
Devere: NO. You can find another healer, like you said.